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Beilstein J. Org. Chem. 2014, 10, 1421–1432, doi:10.3762/bjoc.10.146
Graphical Abstract
Figure 1: Alkaloids produced by Streptomyces strain FORM5.
Figure 2: Part of the total ion chromatogram of the headspace extract of Streptomyces sp. FORM5 with the stru...
Figure 3: Mass spectra of a) (E)-2-(pent-3-en-1-yl)pyridine (streptopyridine E, 8), b) (1Z,3E)-penta-1,3-dien...
Scheme 1: Synthesis of streptopyridines A to E (8–12) and the 2-alkylpyridines 6 and 7.
Figure 4: Total ion chromatograms of the product mixtures of isomers 9–12 synthesized under E-selective (a) a...
Figure 5: Structures of piperidine derivatives 20–26.
Figure 6: a) Mass spectrum of streptopyridine A (12), b) mass spectrum of 12 after feeding of 2 mM 13C2-sodiu...
Scheme 2: Proposed biosynthesis of the streptopyridines. PKS: polyketide synthase; red: reduction; ta: transa...
Figure 7: Compounds detected in the headspace of Streptomyces sp. FORM5.